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71.
In this article, we introduce a general theoretical framework to analyze non-consistent approximations of the discrete eigenmodes of a self-adjoint operator. We focus in particular on the discrete eigenvalues laying in spectral gaps. We first provide a priori error estimates on the eigenvalues and eigenvectors in the absence of spectral pollution. We then show that the supercell method for perturbed periodic Schrödinger operators falls into the scope of our study. We prove that this method is spectral pollution free, and we derive optimal convergence rates for the planewave discretization method, taking numerical integration errors into account. Some numerical illustrations are provided. 相似文献
72.
Parker SF Refson K Williams KP Braden DA Hudson BS Yvon K 《Inorganic chemistry》2006,45(26):10951-10957
The dynamics and bonding of the hydrido complex Ba[ReH9], containing the D3h face-capped trigonal prismatic [ReH9]2- ion, have been investigated by vibrational spectroscopy and density functional theory (DFT). The combination of infrared, Raman, and inelastic neutron-scattering (INS) spectroscopies has enabled observation of all the modes of the [ReH9]2- ion for the first time. We demonstrate that calculations of the isolated [ReH9]2- ion are unable to reproduce the INS spectrum and that the complete unit cell must be considered with periodic DFT to have reliable results. This is shown to be a consequence of the long-range Coulomb potential present. Analysis of the electronic structure shows that the bonding between the rhenium and the hydrogen is largely covalent. There is a small degree of covalency between the prism hydrides and the barium. The counterion is crucial to the stability of the materials; hence, variation of it potentially offers a method to fine-tune the properties of the material. 相似文献
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In the frame of mathematical optimization procedures or parameter fitting the same problem, modeled with partial differential equations depending on a parameter has to be solved many times for different sets of parameters. The reduced basis method may be successful in this frame and recent progress have permitted to make the computations reliable thanks to a posteriori estimators and to extend the method to non linear problems thanks to the “magic points” interpolation. However, in an industrial context, it may not be possible to use the code (for example of finite element type that allows for evaluating the elements of the reduced basis) to perform all the “off-line” computations necessary for an efficient performance of the reduced basis method. We propose here an alternating approach based on a coarse grid finite element the convergence of which is accelerated through the reduced basis. To cite this article: R. Chakir, Y. Maday, C. R. Acad. Sci. Paris, Ser. I 347 (2009). 相似文献
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77.
Crystallographic and magnetic properties of a new structural series of ternary borides with composition R1+εFe4B4 (R = Ce, Pr, Nd, Sm, Gd, Tb, 0.11(Pr) ≤ε≤ 0.15(Tb) are reported. The compounds are built of incommensurate substructures of rare earth atoms (linear strings ?? c?), iron atoms (chains of edge sharing tetrahedra ?? c?),and boron atom pairs. A single crystal X-ray diffraction study of one representative (Sm1.13Fe4B4) based on a commensurate structure model (composition : Sm17(Fe4B4)15, a = 7.07 Å, c ≡ 17cSm ≡ 15cFe= 58.69 Å, space group P42/n) revealed a periodic twist modulation of the Fe tetrahedra chains around c?. Magnetic susceptibility measurements on single crystals of another representative (Nd1.11Fe4B4) revealed ferromagnetic ordering at Tc = 13 K. Above this temperature the magnetic properties are dominated by ferromagnetic inclusions (Fe2B, Nd2Fe14B). 相似文献
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79.
Habold C Dunel-Erb S Chevalier C Laurent P Le Maho Y Lignot JH 《Micron (Oxford, England : 1993)》2003,34(8):373-379
In order to evaluate the potential use of environmental scanning electron microscopy (ESEM) in biology, structural changes of the jejunal villi of rats were studied after periods of fasting and refeeding, using a conventional scanning electron microscope (CSEM) and ESEM. While observation using the CSEM, involves chemical fixation, drying and coating, observation of fresh, unprepared materials can be directly realized with the ESEM. Environmental microscopy provides a relatively new technology for imaging hydrated materials without specimen preparation and conductive coating. Direct observation of biological samples in their native state is therefore possible with an ESEM.
After fasting, the jejunal mucosa is dramatically reduced in size, splits and holes appearing at the tip of the villi. These changes were observed whatever the type of technique used. Artifacts due to the sample preparation for CSEM observation (drying, coating) can therefore be excluded. However, CSEM and ESEM must be used jointly. While, CSEM must be preferred for surface analysis involving high magnifications, ESEM observation, on the other hand, can prove valuable for determining the living aspect of the samples. 相似文献
80.
Single crystal X-ray diffraction measurements on MxMo3S4 compounds (M = Cu, Ag, Sn, In) yield evidence for the existence of a charge transfer from the interstitial element M to the Mo6S8 building blocks. The importance of this transfer was estimated from the contraction of the Mo6 octahedron as a function of the valency and the concentration of the cations. It is suggested that this effect stabilises the structure and has a strong influence on the superconducting transition temperature. Bonding is discussed using a simple valence bond model which is based on the electron requirement of the Mo6 octahedron to form 12 covalent bonds. 相似文献